Statistical modeling and optimization of heavy metals (Pb and Cd) adsorption from aqueous solution by synthesis of Fe<inf>3</inf>O<inf>4</inf>/SiO<inf>2</inf>/PAM: isotherm, kinetics, and thermodynamic

Abstract

In this study, magnetic material was synthesized using iron salts, then silicon-specific material was used to gain porosity, straight-chain polyacrylamide (PAM) was modified to give the surface functional properties, and the final product synthesized Fe3O4/SiO2/PAM nanocomposite material. Heavy metal (Pb and Cd) removal studies were carried out with the synthesized composite material, considering the central composite design and response surface methodology (CCD-RSM) optimization model. The effects of various parameters, for example, the initial concentration, pH, adsorbent dose, temperature and contact time, were investigated as a part of this study. To optimize these parameters, the CCD-RSM model was applied to design the experiments. Analysis of variance (ANOVA) was applied to evaluate statistical parameters and investigate interactions of variables. In the designed experimental set, the amount of adsorbent (30 mg), pH 7.0 value, temperature (40 °C), initial concentration of Pb (80 mg/L) and Cd (20 mg/L) and 90 min contact time were determined as the optimum conditions. The high coefficient of determination of both metals showed good agreement between experimental results and predicted values (R2 0.99; 0.95). TEM, SEM, XRD, FTIR, BET and Zeta potential analyses were performed to characterize the structure and morphology of the adsorbent. In Pb2+ and Cd2+ heavy metal removal studies, maximum adsorption capacities were determined as 66.54 and 13.22 mg/g, respectively. Additionally, adsorption isotherms, adsorption kinetics and thermodynamic modeling studies were conducted. Features such as large surface area and high adsorption capacity of the synthesized nanoparticles were observed. In this study, Fe3O4/SiO2/PAM demonstrated its potential as an effective adsorbent for the removal of heavy metal ions present in simulated wastewater samples. In particular, we can say that the material has a strong selectivity, as well as a high affinity for Pb(II) ions.

In this study, magnetic material was synthesized using iron salts, then silicon-specific material was used to gain porosity, straight-chain polyacrylamide (PAM) was modified to give the surface functional properties, and the final product synthesized Fe3O4/SiO2/PAM nanocomposite material. Heavy metal (Pb and Cd) removal studies were carried out with the synthesized composite material, considering the central composite design and response surface methodology (CCD-RSM) optimization model. The effects of various parameters, for example, the initial concentration, pH, adsorbent dose, temperature and contact time, were investigated as a part of this study. To optimize these parameters, the CCD-RSM model was applied to design the experiments. Analysis of variance (ANOVA) was applied to evaluate statistical parameters and investigate interactions of variables. In the designed experimental set, the amount of adsorbent (30 mg), pH 7.0 value, temperature (40 °C), initial concentration of Pb (80 mg/L) and Cd (20 mg/L) and 90 min contact time were determined as the optimum conditions. The high coefficient of determination of both metals showed good agreement between experimental results and predicted values (R2 0.99; 0.95). TEM, SEM, XRD, FTIR, BET and Zeta potential analyses were performed to characterize the structure and morphology of the adsorbent. In Pb2+ and Cd2+ heavy metal removal studies, maximum adsorption capacities were determined as 66.54 and 13.22 mg/g, respectively. Additionally, adsorption isotherms, adsorption kinetics and thermodynamic modeling studies were conducted. Features such as large surface area and high adsorption capacity of the synthesized nanoparticles were observed. In this study, Fe3O4/SiO2/PAM demonstrated its potential as an effective adsorbent for the removal of heavy metal ions present in simulated wastewater samples. In particular, we can say that the material has a strong selectivity, as well as a high affinity for Pb(II) ions.